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From what I recall, a PC will only list USB as an option if it has a bootable partition and is inserted at that timeI've tried all the USB ports, front and back. The issue is not with the USB stick itself, but with my old PC that doesn't have a 'boot from USB' option (see screenshots above). I expect I'll just have to get some double layer DVDs and download the ISO file onto that, then boot the old PC from the CD drive.
It’s worth creating a bootable usb yourself and trying that before buying things, only takes 5 minutes.