SpyderTracks
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I would contact PCS and get them replaced with 2 x 16.I think I have exhausted the amount of testing I can do and would be good to get everyone's view on what I should potentially do next.
In summary, I have learned the following:
1. both my old and new ram sets ( 2 sets of 2 x 8 GB) work fine in slots A2/B2 at 3600MHz
2. When I put either set in slots A1/B2 I get boot errors until I reduce the speed to 3266 MHz
3. I can have all four sticks in the machine and boot at 3266MHz and the system appears stable, however when I run memtest the errors quickly rack up - I got more than 7000 errors in just under 40 mins of testing - see link below
Memtest
justpaste.it
So my conclusions are the following:
A. The Ram does not appear to be faulty based on point 1 above
B. The bios for the Asus B550 board is not yet stable and a future update may resolve it, or
C. I have faulty ram slots / motherboard or potentially CPU
Therefore I either RMA the system or wait for a Bios update. Or potentially try and see if I can get hold of 2 x 16 GB sticks, which may work in the A2/B2 slots.
What do you guys think?
The performance impact from 2 x 16 is minimal really, certainly not worth RMA.
I'm not convinced there are issues with the RAM, I think they're healthy sticks, I think it's a board issue, as you say, very likely the BIOS not coping well with the 4 DIMM setup over 3200MHz
The testing you've done is very thorough, I would point PCS to this thread and give them a call.